The Avengers - Season 4 - Eps 21: A Touch of Brimstone
When a group of hoaxsters called the Hellfire Club mix murder with their mischief, Steed and Emma demonstrate a few tricks of their own. The whalebone corset, high laced boots and spiked dog-collar Emma wears as the "Queen of Sin" were designed by Diana Rigg herself, and resulted in A Touch of Brimstone being banned from American TV.
About The Avengers

Title: The Avengers
First Air Date: 1961-01-07
Last Air Date: 1969-05-21
Status: Ended
Rating: 7.725/10 (from 142 votes)
Language: EN
Seasons: 7
Total Episodes: 161
Network: ITV1
Genres: Action & Adventure, Crime, Sci-Fi & Fantasy
Production Companies: Associated British Picture Corporation, Associated British Corporation, ABC Weekend Television
Synopsis
A quirky spy show of the adventures of eccentrically suave British Agent John Steed and his predominantly female partners. Jonathan Steed - an urbane, proper gentleman spy - teams with various assistants throughout the series' run, including Dr. David Keel, Cathy Gale, Emma Peel and Tara King, to repeatedly save the world from diabolical schemes plotted by equally diabolical evil-doers (among them robots and man-eating monsters).
Cast

Patrick Macnee
John Steed

Linda Thorson
Tara King

Ian Ogilvy

William Lucas